New Extraction System for Lithium from Brine with High Magnesium Content     

HE Jing  YANG Lixin  WANG Yi  FU Mi 《《地质学报》英文版》2014,88(Z1):333-334

正Lithium is an important element with a wide variety of applications,especially in lithium ion batteries and in the exploration of nuclear energy.Salt lake brine is the most abundant lithium source available in world,comp-rising70%~80%of all known lithium deposits.Lithium can be abstracted from brines with low magnesium content and processed into kinds of lithium compound in Atacama and Hombre Muerto of South America(Nie et al.,2013).  相似文献   

中国锂矿成矿规律概要   总被引：50，自引：2，他引：48  

李建康  刘喜方  王登红 《地质学报》2014,88(12):2269-2283

锂资源是我国高新产业发展的保障性资源和战略性资源之一.我国锂矿资源丰富,主要集中在西藏、青海、四川和江西4省(区).锂矿床类型以硬岩型为主,盐湖锂矿虽然储量巨大,但开发利用技术尚待发展.硬岩型锂矿又以伟晶岩型为主,集中分布在新疆阿尔泰和川西甲基卡等矿集区;成矿时代以中生代最为重要;成矿大地构造背景以造山运动之后的稳定环境最具特色.本次在对全国151处锂矿矿产地资料系统梳理的基础上,深入总结了全国锂矿的成矿规律,厘定出14个以锂为主的矿床成矿系列,认为伟晶岩型、花岗岩型和盐湖沉积型3个锂矿预测类型应该作为重点预测类型,并划分出12个成锂带,圈定出5个重要勘查评价区,并编制了“中国成锂带分布图”等系列图件,为本次全国锂矿资源潜力评价预测工作和今后的找矿工作提供了理论依据.  相似文献   

自动气象站蓄电池预测性维护的监测系统评定     

张曼  范雪波  李林  常晨 《干旱气象》2013,(4):831-834

为提高自动气象站蓄电池的维护效率,本文将预测性维护引入气象保障领域,通过对蓄电池预测性维护的技术要点、测试方案及流程等的介绍,选取3种不同劣化程度的蓄电池依次进行离线状态测试、浮充状态测试以及放电测试,通过数据对比分析初步给出了蓄电池预测性维护监测系统的综合评定。结果表明,在浮充状态下,监测系统电压和内阻的测试精度良好,能够很好地测试出蓄电池在不同健康状况下的电压与内阻值,即对报废电池、具有一定劣化程度电池和新电池的测试数据存在显著差别,在自动气象站蓄电池预测性维护中可利用浮充状态下测得的内阻数据对蓄电池劣化程度进行有效判别。  相似文献   

川南地区二叠系黏土型锂矿地质特征及找矿潜力     

文俊 《地质论评》2024,70(S1):89-90

  相似文献   

拉萨地块西段中新世赛利普超钾质火山岩富集地幔源区和岩石成因:Li同位素制约   总被引：1，自引：0，他引：1  

田世洪  胡文洁  侯增谦  莫宣学  杨竹森  赵悦  侯可军  朱弟成  苏嫒娜  张兆卿 《矿床地质》2012,31(4):791-812

作为一种“非传统稳定同位素”,锂同位素地球化学研究已经成为近年来国际上研究的热点之一.文章成功应用锂同位素对青藏高原西南部赛利普超钾质火山岩进行了示范研究.研究表明,赛利普超钾质火出岩的w(Li)为11.2×10-6～22.9× 10-6,同位素组成δ7Li为1.2‰～+3.5‰,平均值为0 2‰,与平均上地壳的相当.超钾质火山岩的锂同位素组成与岩浆结晶分异程度参数之间不存在任何相关性,这表明在超钾质火山岩结晶分异过程中没有发生明显的锂同位素分馏,锂同位素组成特征反映了其形成时的源区特征.超钾质火山岩的锂同位素组成变化范围达4.7‰,并且与pb-Sr-Nd同位素和岩浆结晶分异参数之间亦无任何相关性,表明锂同位素异常可能反映了不均匀源区岩石特征.通过计算模拟以及与前人的类似研究成果进行对比,笔者认为俯冲印度地壳而不是特提斯洋壳(包括沉积物)的流体/熔体参与了超钾质火山岩的源区富集,并在此基础上提出了超钾质火山岩成因模式.  相似文献   

A brief review of isotopically light Li – a feature of the enriched mantle?     

《International Geology Review》2012,54(9):964-976

Lithium isotope geochemistry is increasingly being used to trace deep-earth processes, reflecting the observed large variation of Li isotope ratios in mantle-derived rocks, including peridotite xenoliths associated with ancient continents. We briefly review the Li isotopic compositions of major geochemical reservoirs, the assumed mechanisms of Li isotopic fractionation, and, in particular, the origins of isotopically light Li in mantle-derived rocks based on the latest developments in Li isotope geochemistry. Comparison of Li isotope data with existing Sr-Nd isotope ratios reflects the subduction-recycling of ancient oceanic crust and the reappearance of Li in volcanic rocks. This circulation may play an important role in generating the isotopically light-Li component in the mantle – perhaps the enriched mantle end member defined by the Sr-Nd isotopic compositions of oceanic basalts.  相似文献   

Separation and Precise Measurement of Lithium Isotopes in Three Reference Materials Using Multi Collector‐Inductively Coupled Plasma Mass Spectrometry   总被引：2，自引：0，他引：2  

TIAN Shihong  HOU Zengqian  SU Ain  HOU Kejun  HU Wenjie  LI Zhenzhen  ZHAO Yue  GAO Yanguang  LI Yanhe  YANG Dan  YANG Zhusen 《《地质学报》英文版》2012,86(5):1297-1305

Lithium separation technique for three reference materials has been established together with precise determination of lithium isotope using a Neptune multi collector-inductively coupled plasma mass spectrometry (MC-ICP-MS). The solutions of lithium element standard reference materials, potassium, calcium, sodium, magnesium and iron single element, were used to evaluate analytical methods applied. Three separate stages of ion-exchange chromatography were carried out using organic cation-exchange resin (AG 50W-X8). Lithium was enriched for the three stages using different eluants, which are 2.8 M HCl, 0.15 M HCl and 0.5 M HCl in 30% ethanol, respectively. The columns for the first and second stages are made of polypropylene, and those for the third stage are made of quartz. Total reagent volume for the entire chemical process was 35 mL for three reference materials. The recovery yielded for the three stages is 98.9–101.2% with an average of 100.0%, 97.6–101.9% with an average of 99.9%, and 99.8–103.3% with an average of 100.6%, respectively. The precision of this technique is conservatively estimated to be ±0.72–1.04‰ (2σ population), which is similar to the precision obtained by different authors in different laboratories with MC-ICP-MS. The δ7Li values (7Li/6Li relative to the IRMM-016 standard) determined for andesite (AGV-2) and basalt (BHVO-2) are 5.68‰ (n=18), 4.33‰ (n=18), respectively. The δ7Li value (7Li/6Li relative to the L-SVEC standard) determined for IRMM-016 is –0.01‰ (n=15). All these analytical results are in good agreement with those previously reported. In addition, the results for the same kinds of samples analyzed at the MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, are consistent with those obtained at the Plasma Laboratory, University of Maryland, within analytical uncertainty. According to these experiment results, it is concluded that this proposed procedure is a suitable method for determining the lithium isotopic composition of natural samples.  相似文献   

华北克拉通岩石圈地幔的锂同位素特征与熔体改造作用     

汤艳杰  张宏福 《矿物岩石地球化学通报》2019,(2):217-223,444-445

华北克拉通是显生宙以来全球古老克拉通破坏最为剧烈的地区。华北克拉通破坏及其相关的科学问题引起了国内外地质学家的广泛关注。有关华北克拉通破坏的研究已取得了许多重要进展,使我们认识到其破坏不仅表现为岩石圈厚度的剧烈减薄,更重要的是岩石圈地幔的物质组成与性质发生了巨大转变,即从古生代克拉通型转变为新生代大洋型。本文在综述华北地幔捕虏体锂同位素地球化学特征的基础上,进一步揭示了华北岩石圈地幔高度不均一的组成特征,以及不同来源的熔体对岩石圈地幔的改造作用,为深入认识华北岩石圈地幔的转变过程提供进一步的制约。  相似文献   

锂同位素在伟晶岩矿床成因研究中的应用          下载免费PDF全文

李贤芳  张玉洁  田世洪 《中国地质》2019,46(2):419-429

稀有金属矿产对现代工业和科技的发展极其重要,伟晶岩矿床作为稀有金属的主要来源,其成因与成矿作用有待深入研究,普遍争论的成因模式包括:花岗岩结晶分异、地壳部分熔融以及岩浆液态不混溶。研究表明地壳深熔过程中锂同位素不发生有意义的分馏,因此在解决花岗岩和伟晶岩的岩浆源区性质方面提供了强有力的证据。文章主要从花岗伟晶岩的成因、锂同位素分馏机制以及锂同位素在伟晶岩矿床中的应用三个方面系统综述了国内外近年来取得的一些研究进展。国内外学者以锂同位素分馏机制详细论述了花岗伟晶岩的Li同位素组成,认为伟晶岩矿床的成因主要为花岗岩结晶分异或地壳部分熔融。但是锂同位素应用于伟晶岩矿床成因方面的研究还不够成熟,需要开展更多的工作。  相似文献   

粉末压片制样-X射线荧光光谱法测定锂云母中的高含量氟   总被引：1，自引：1，他引：0  

曾江萍  李小莉  张楠  王家松  魏双  王娜 《岩矿测试》2019,38(1):71-76

锂云母中的氟含量很高(1. 36%～8. 71%),在焙烧锂云母矿物时锂的浸出率随着含氟量的增加而逐步下降,随着锂云母脱氟率的提高,锂的浸出率也相应提高,准确测定锂云母中的氟、控制氟含量可为确定焙烧过程的工艺条件、设备参数及成本提供依据。目前氟的测定主要采用离子选择电极法,但过程复杂、分析时间长且空白值高。本文采用粉末直接压片制样X射线荧光光谱法测定锂云母中的氟,氟的检出限为46±4μg/g。将锂矿石标准物质和人工配制校准物质制成工作曲线,经验系数校正基体效应和谱线干扰,方法精密度(RSD,n=10)为1. 03%。采用本法分析由标准样品合成的样品,测定值与理论值吻合良好;用实际样品验证,测定结果与离子选择电极法的测定值相符。本法适用于分析锂云母中0. 68%～9. 14%的氟。  相似文献